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Nucleic Acids Research, 1988, Vol. 16, No. 10 4583-4594
© 1988

Articles

Synthesis of hexanucleotide analogues containing diisopropylsilyl internucleotide linkages

James F. Cormier and Kevin K. Ogilvie*

Department of Chemistry, McGill University 801 Sherbrooke St. W., Montreal, Quebec H3A 2K6, Canada

* To whom correspondence should be addressed

Received March 9, 1988. Revised March 17, 1988. Accepted March 17, 1988.

The synthesis of two silyl-linked hexanucleotide analogues is described. Hypochromicity and CD measurements indicate that the thymidine hexanucleotide analogue bears a strong resemblance to its phosphodiester-linked counterpart.


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