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Nucleic Acids Research, 1975, Vol. 2, No. 3 353-360
© 1975

Articles

Protonated polynucleotide structures. 16. Thermodynamics of the melting of the acid form of polycytidylic acid

Wilhelm Guschlbauer

Service de Biochimie. Bât. 142, Centre d'Etudes Nucléaires de Saclay B.P. No2, F-91190 - Gif-sur-Yvette, France

Received December 6, 1975. A phase diagram (pH, ionic strength, temperature) for the double helical form of poly(c) is presented. The thermodynamic analysis of these data shows that poly(c) behaves essentially as cytidine, if the electrostatic (ionic strength) contributions and the free energy of double helix formation are considered and taken into account.


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