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Nucleic Acids Research, 1977, Vol. 4, No. 7 2487-2494
© 1977

Articles

Photoproducts from DNA pyrimidine bases and polycyclic aromatic hydrocarbons

G. Michael Blackburn*, R. G. Fenwick, G. Lockwood and G. M. Williams

Department of Chemistry, The University Sheffield S3 7HF, UK

*To whom all correspondence should be addressed

Received May 25, 1977. The major photoproduct formed between benzo[a]pyrene and thymine is identified as 1-(benzo[a]pyren-6-yl)-thymine by means of spectroscopic analysis and isotopic syntheses. Irradiation of 1-methylcytosine hydrochloride and anthracene gives two isolable photoproducts of which one is assigned the structure 5-(anthracen-9-yl)-1-methylcytosine.


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